For some unusual reason, I find this couple very appealing while others might disagree. I guess the sense of a innocent girl and a trouble minded guy together seems more interesting than your average innocent girl and boy like Kimi no Todoke.

I get this surging feeling when I think of this girl in love with someone totally opposite of her in personality wise, not popularity standards. It makes me eager to understand such love development. It's a shame in my eyes that Orihime can never be with Ulquiorra since Bleach is not exactly a love anime. However I will imagine it possible through fanfiction. lol.